Hydrogeochemistry and strontium isotopes in the Arno River Basin (Tuscany, Italy): Constraints on natural controls by statistical modeling   总被引：2，自引：0，他引：2  

B. Nisi  A. Buccianti  O. Vaselli  G. Perini  F. Tassi  A. Minissale  G. Montegrossi 《Journal of Hydrology》2008,360(1-4):166-183

In this paper the chemistry of major and trace elements and, for the first time, strontium isotopic ratios measured in running waters from the Arno River Basin (Tuscany, central-northern Italy) and thermal springs discharging in the same hydrographic system are presented and discussed. Classical graphical methods (e.g. mixing diagrams) have here been improved to identify, in a correct statistical sample space, extreme chemical compositions attributable to the action of geochemical processes and/or inherited from specific lithologies (namely contributions or components 1, 2 and 3) to be used in inverse modeling procedures, due to the absence of clear end-members. A linear least squares problem, with non-negativity constraints and distances, as required for compositional data (convex linear mixing) was solved by considering the contribution of the most discriminant variables given by the ⁸⁷Sr/⁸⁶Sr isotopic ratios and the concentration of Ca²⁺, Mg²⁺, Sr and Rb. Following such approach, it can be assumed (p < 0.05) that component 1, characterized by a Ca²⁺(Mg²⁺)– radiogenic-rich (⁸⁷Sr/⁸⁶Sr = 0.71274; Rb/Sr = 0.039), represents a dominant feature at basin scale, with a weight ranging from 69% to 100%. Much lower percentages are related to component 2, represented by a Ca²⁺(Mg²⁺)– facies with intermediate ⁸⁷Sr/⁸⁶Sr (0.70874) and low Rb/Sr (2.8 × 10⁻⁴) ratios and component 3, identified by Ca²⁺– facies with less radiogenic ⁸⁷Sr/⁸⁶Sr (0.70827) and low Mg²⁺/Ca²⁺ (0.011) ratios. These components are mainly dominated by the dissolution of evaporitic rocks and/or mixing with thermal waters in the southern part of the Arno River Basin and by dissolution of the carbonatic fraction, kinetically favored with respect to that of the silicatic minerals, in the upper reaches of the main course and its tributaries, respectively.  相似文献   

Pyrite formation driven by MSW landfill leachate in the Madrid Basin, Spain     

Ricardo Castelló  Clemente Recio  Pilar Morillas  Carmen Vizcayno 《Environmental Geology》2008,54(4):679-688

The role of municipal solid waste (MSW) landfill leachate on the genesis of minor amounts of pyrite associated with gypsum in an otherwise predominantly evaporitic sequence was studied in geological and geochemical terms. The potential association between landfill leachate and the conditions required for bacterial reduction of sulfate and fixation of H₂S as pyrite were examined. The lithological column was generally found to contain little or no Fe. The δ³⁴S values for sulfates were consistent with previously reported data; however, the measured δ¹⁸O values were slightly higher. Sulfides disseminated in the marl/lutite exhibited higher δ³⁴S values (≈−8‰) than gypsum-coating pyrite crystals (δ³⁴S < −30‰). Dissolution of gypsum to sulfate and the supply of metabolizable organic matter and Fe required for H₂S fixation as sulfides may have originated from landfill leachate. Intermittent availability of leachate, a result of the precipitation regime, can facilitate sulfur disproportionation and lead to fractionations as high as   相似文献   

松辽盆地三肇凹陷葡萄花油层成藏模式初探   总被引：11，自引：5，他引：6       下载免费PDF全文

孙雨  马世忠  刘云燕  刘宗堡  于利民 《地质科学》2008,43(4):746-757

运用源控含油气系统理论与综合分析技术,按成藏“层次分析”方法,通过对生、储、盖、圈(闭)静态要素及其内生、排、运、聚、散(失)动态过程的综合研究,对松辽盆地中央坳陷的三肇凹陷葡萄花油层成藏条件进行探讨,提出了以次级凹陷为中心、不同类型的油气聚集带紧邻并围绕次级凹陷最低部位呈环带状分布的大型凹陷内成藏模式,并进一步提出永乐次级凹陷中心及其三级聚油环带及徐家围子次级凹陷以西为"网式"运聚特征;在凹陷级成藏模式的指导下,通过对大面积密井网开发区综合解剖,提出三级构造带中单个的局部构造圈闭(群)、单个的(局部构造——)岩性圈闭(群)控油和成藏规律,为认识本区基本控油单元、油水分布规律、油气勘探及扩大新探区提供重要的理论依据。  相似文献   

鱼卡煤田大煤沟组高分辨率层序地层特征及聚煤规律   总被引：1，自引：0，他引：1  

白生海  田景春  肖玲  张翔 《地层学杂志》2008,32(4)

利用高分辨率层序地层学理论和技术方法,综合地震、测井、岩芯和煤质资料对柴达木盆地北缘鱼卡煤田中下侏罗统大煤沟组地层河湖三角洲沉积体系进行高分辨率层序地层学分析,从中识别出短期、中期、长期3个级别的基准面旋回层序,划分出向上"变深"非对称型、向上"变浅"非对称型及对称型3种短期基准面旋回基本结构类型。依据等时地层对比法则进行不同级次基准面旋回层序的联井对比,建立了大煤沟组的等时地层格架,在等时地层格架内进行了煤层对比,并在等时地层格架内分析了聚煤规律。  相似文献   

海相碳酸盐岩层系不整合量化研究及其意义——以四川盆地北部二叠系为例   总被引：2，自引：1，他引：1  

李儒峰  郭彤楼  汤良杰  陈国飞 《地质学报》2008,82(3):407-412

本文以四川盆地北部二叠系为例,将层序地层分析和沉积盆地波动过程分析相结合,提出了运用沉积波动过程分析研究沉积记录不完整性的量化方法,该方法可以相对准确地定量描述盆地形成演化过程中的升降运动,恢复无地层"记录"中的沉积-剥蚀过程,进而定量分析盆地的沉积-剥蚀过程、计算沉积间断(不整合)内的地层剥蚀量、认识其时空分布规律.同时,通过实际钻井及"人工井"的波动过程分析,结合地震剖面解释成果,可以作出主要不整合的空间分布图、各层位的剥蚀厚度图和原始厚度图、各期构造的剥蚀量分布图等重要基础图件,为盆地进一步系统分析及盆地模拟打好基础,结合沉积相研究及构造样式分析还可分析盆地沉积中心、生油层、盖层、储层等在时空中的变化规律.由于沉积盆地的升降波动过程直接影响着盆地的埋藏史、热史和生、排烃史,因此通过沉积波动过程的系统分析不仅能正确建立盆地演化的地质模型,还可以正确认识油气形成与分布规律,有效指导油气勘探.  相似文献   

珠江流域夏半年降水的预测     

刘艳群  粱必骐  唐宇 《气象科技》2008,36(2):145-149

采用珠江流域1954～2003年月降水资料,以及前期太平洋海温场和北半球500 hPa高度场月平均资料,利用主分量逐步回归预测模型,对该流域夏半年(4～9月)降水分布进行主分量计算和预测.结果表明:对前25个主分量的预测就能很好地预测珠江流域夏半年降水的变化,2004～2006年预测结果与实况较接近.预测因子取自500 hPa高度场和海温场的主分量,为降水的预测提供大量有用信息.该方法在实际业务中有一定的应用价值.  相似文献   

岩性油藏地震描述技术在准噶尔盆地春光油田的应用   总被引：1，自引：1，他引：0  

穆玉庆 《海相油气地质》2010,15(4)

准噶尔盆地春光油田新近系沙湾组岩性油藏埋藏浅、厚度薄、成岩作用差,勘探效果不理想。利用层拉平切片技术确定有利储集相带、分频技术雕刻砂体、"类亮点"特征检测流体、进一步采用拟声波+电阻率反演两步法鉴别流体,这一技术方法系列在春光油田的实际应用效果良好。用拟声波+电阻率反演两步法可以检测出无亮点特征的含油砂体或含水砂体。对于不具备"类亮点"特征的滩坝砂油藏的勘探,可由原来的应用"类亮点"特征直接找油转为寻找有效圈闭,并在此基础上应用合适的流体检测技术,这同样可以发现有利的滩坝砂油藏。  相似文献   

塔里木盆地肖尔布拉克剖面下丘里塔格组层序地层及其油气勘探意义   总被引：2，自引：0，他引：2  

陈永权  周新源  杨海军  潘文庆  李国会 《地层学杂志》2010,34(1)

塔里木盆地晚寒武世台地沉积区发育大量的白云岩,其中蕴涵着大量白云岩储层。以柯坪地区肖尔布拉克剖面为例,首次提出了以地层单层厚度为划分依据划分层序地层的方法,结合岩石学分析结果,确定了肖尔布拉克剖面寒武系下丘里塔格组白云岩的层序地层四分方案,塔中地震资料表明该四分方案可能适用于塔里木盆地整个西部台地区。根据肖尔布拉克剖面下丘里塔格组白云岩的岩石学分析,埋藏岩溶作用产生的溶蚀空间为该白云岩段的主要储集空间,因此可将下丘里塔格组白云岩储层定义为"埋藏岩溶型白云岩储层",该储层发育位置与层序界面有密切关系,一般沿层序界面之下发育。根据上寒武统白云岩的层序地层四分方案,与层序地层对储层的控制作用,提出了塔里木盆地西部台地区上寒武统"埋藏岩溶型复式白云岩储层"概念,并给予了阐释。  相似文献   

Provenance of freshwater pulses in the Gulf of Mexico during the last deglaciation     

T. Sionneau  V. Bout-Roumazeilles  N. Tribovillard 《Quaternary Research》2010,74(2):235-245

During the last deglaciation, the decaying Laurentide Ice Sheet (LIS) delivered huge volumes of meltwater toward the Gulf of Mexico. The present investigation of clay mineralogy and grain-size characteristics of terrigenous sediments deposited in the Orca Basin (Gulf of Mexico) offers a unique opportunity to link the marine record of these meltwater floods with the reconstructed continental glacial history and the modeled drainage patterns. Five peculiar sedimentary levels, characterized by high smectite content and low CaCO₃ content, were identified and occurred simultaneously with major meltwater floods. According to recently published clay mineral distribution maps for North America, these results help to pinpoint the southwestern margin of the LIS as a main contributor to most of the meltwater discharges. In addition, the peculiar mineralogical composition (illite and chlorite-rich) of the sediments characterizing the meltwater episode associated with Heinrich event 1 suggests a provenance from the Great Lakes area, supporting the interpretation of destabilization of the LIS southeastern margin during this event. Decreased terrigenous contribution associated with changing provenance of sediments after 12.9 cal ka BP suggests strong modifications of the continental hydrography in relation to Lake Agassiz history and changes in the morphology of Mississippi delta due to rising sea level.  相似文献   

塔里木盆地区域地下水环境同位素特征及其意义   总被引：12，自引：0，他引：12  

李文鹏  郝爱兵  郑跃军  刘斌  于德胜 《地学前缘》2006,13(1):191-198

以大量水环境同位素样品测试结果为依据,对塔里木盆地的区域水环境同位素特征进行了分析,得出了一些有意义的认识:(1)塔里木盆地不同14C年龄的地下水的δD、δ18O值差异不明显,反映了水资源形成区在最后冰期和冰后期气温相差不大,推测是由于新构造运动使山体隆升,同一位置因高程变化产生的气温变化弥合了气候的变化,这一特征使我们难以运用δD-δ18O关系区别古水(冰期)与现代水(冰后期)。(2)在δD-δ18O关系图上,沿大气降水线可把盆地内主要河流及其补给形成的地下水大致圈定在3个域内,这3个域的区别不是大气环流作用的结果,而是河流源区山脉高程效应的反映。(3)与西北内陆盆地其他大型河流比较,阿克苏河流域下游承压自流水的14C年龄小得多,这是由阿克苏河径流量大、下游为河槽洼地、不完全具备山前倾斜平原水文地质特征等决定的。阿克苏河下游承压水水循环交替迅速,开发潜力较大,在西北内流盆地中是一个特例。(4)塔克拉玛干沙漠第四系松散层地下水主要是从盆地南缘侧向补给的,在沙漠腹地由深部向浅部顶托排泄。盆地内深层油田水处于高度封闭的滞留状态,与上部松散沉积层地下水之间基本没有联系。  相似文献